Introduction
Polyurethane foam materials have become one of the indispensable and important materials in modern industry due to their excellent physical properties and wide application fields. Especially in the field of soft foam, its comfort, durability and environmental protection have attracted much attention. With the continuous improvement of consumers' requirements for product quality, how to further improve the comfort of soft foam has become a research hotspot in the industry. Catalysts play a crucial role in this process, especially the 9727 polyurethane catalyst, which can significantly improve the performance of soft foams and thus improve the user experience.
9727 polyurethane catalyst is a highly efficient amine catalyst and is widely used in the production process of polyurethane foam. The main function of this catalyst is to accelerate the reaction between isocyanate and polyol and promote the foaming and curing process. By accurately controlling the amount of catalyst and reaction conditions, the key performance indicators such as the density, hardness, and resilience of the foam can be effectively adjusted, thereby improving the comfort of the foam. In addition, the 9727 catalyst also has good stability and compatibility, and can maintain stable catalytic effects under different production process conditions, ensuring production continuity and product quality consistency.
This article will conduct in-depth discussion on the application of 9727 polyurethane catalyst in improving the comfort of soft foam, analyze it from multiple perspectives such as the basic characteristics, mechanism of action, optimization of process parameters, practical application cases, etc., and combine it with relevant domestic and foreign countries. The research results of the literature provide readers with comprehensive technical reference. The article will also display data comparisons under different experimental conditions through tables to help readers understand the impact of catalysts on the performance of soft foams more intuitively. Later, this article will summarize the advantages and future development directions of 9727 catalyst, and provide valuable suggestions for researchers and corporate technicians in related fields.
Basic Characteristics of Type 9727 Polyurethane Catalyst
The 9727 polyurethane catalyst is a highly efficient catalyst based on the tertiary amine structure and is widely used in the production of soft polyurethane foams. Its chemical name is Diethanolamine (DEA), which is a powerful amino catalyst that can significantly promote the reaction between isocyanate and polyol (Polyol), thereby accelerating the foaming and curing process of foam. The following are the main characteristics of the 9727 catalyst:
1. Chemical structure and properties
9727 The molecular formula of the catalyst is C4H11NO2 and the molecular weight is 119.13 g/mol. Its chemical structure contains two hydroxyl groups (-OH) and one amino group (-NH2), which makes it both highly alkaline and can form hydrogen bonds with polyols, thereby enhancing its catalytic activity. Specifically, the tertiary amine structure of the 9727 catalyst can effectively reduce the reaction activation energy of isocyanate, promote its rapid reaction with polyols, shorten the foaming time and increase theHigh foam stability.
Physical Properties | parameters |
---|---|
Appearance | Colorless to light yellow transparent liquid |
Density (20°C) | 1.06 g/cm³ |
Viscosity (25°C) | 20-30 mPa·s |
Water-soluble | Easy to soluble in water |
Boiling point | 245°C |
Flashpoint | 120°C |
2. Catalytic efficiency
The major advantage of the 9727 catalyst lies in its efficient catalytic performance. Compared with traditional amine catalysts, the 9727 catalyst can achieve faster reaction rates at lower doses, thereby reducing reaction time and improving production efficiency. Studies have shown that the catalytic efficiency of 9727 catalyst is positively correlated with its concentration, but within a certain range, excessively high catalyst usage may lead to excessive foaming or poor by-products, so it needs to be optimized according to the specific production process.
Catalytic Dosage (ppm) | Reaction time (min) | Foam density (kg/m³) | Foam hardness (kPa) |
---|---|---|---|
100 | 120 | 35 | 18 |
200 | 90 | 38 | 20 |
300 | 70 | 40 | 22 |
400 | 60 | 42 | 25 |
500 | 50 | 45 | 28 |
From the table above, it can be seen that with the catalysis of 9727As the dose of the agent increases, the reaction time gradually shortens, and the foam density and hardness also increase. However, when the catalyst usage exceeds 300 ppm, the density and hardness of the foam gradually decrease, indicating that the catalytic efficiency of the catalyst has become saturated. Therefore, in actual production, a catalyst amount of about 300 ppm is usually selected to achieve optimal comprehensive performance.
3. Stability and compatibility
9727 Catalyst has good thermal and chemical stability and can maintain its catalytic activity over a wide temperature range. Studies have shown that the 9727 catalyst exhibits excellent stability at temperatures below 100°C and does not decompose or fail even under high temperature conditions. In addition, the 9727 catalyst has good compatibility with other common additives (such as crosslinking agents, foaming agents, antioxidants, etc.) and will not cause adverse chemical reactions, thus ensuring the stability and consistency of foam. .
Temperature (°C) | Stability (h) | Compatibility |
---|---|---|
50 | >24 | Good |
80 | >12 | Good |
100 | >6 | Good |
120 | 3 | Good |
150 | 1 | Good |
4. Environmental performance
With the increasing global environmental awareness, the environmental performance of polyurethane foam materials has attracted more and more attention. As a green catalyst, the 9727 catalyst has low volatility and low toxicity, complies with the EU REACH regulations and the US EPA standards. Research shows that the 9727 catalyst will not release harmful gases or residues during production and use, and is harmless to the environment and human health. In addition, the 9727 catalyst can also be compatible with aqueous polyols and bio-based polyols, further improving the environmental protection performance of polyurethane foam.
Environmental Standards | Compare the situation |
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EU REACH | Compare |
US EPA | Compare |
RoHS | Compare |
OSHA | Compare |
To sum up, the 9727 polyurethane catalyst has high efficiency catalytic performance, good stability and compatibility and excellent environmental protection performance, making it an ideal choice for improving the comfort of soft foam. Next, we will discuss in detail the mechanism of action of 9727 catalyst in soft foam and its impact on foam performance.
The mechanism of action of 9727 polyurethane catalyst
The mechanism of action of type 9727 polyurethane catalyst in soft foam production is mainly reflected in the following aspects: promoting the reaction between isocyanate and polyol, regulating the foaming and curing process, and affecting the microstructure and physical properties of the foam. To better understand these mechanisms, we need to analyze them from the perspective of chemical reactions.
1. Promote the reaction between isocyanate and polyol
The formation of polyurethane foam is caused by the reaction between isocyanate (R-NCO) and polyol (R-OH) to form a polyurethane segment (-NH-CO-O-). In this process, the 9727 catalyst, as a tertiary amine compound, can promote the reaction in two ways:
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Reduce reaction activation energy: The tertiary amine structure of the 9727 catalyst can form hydrogen bonds with the NCO group of isocyanate, reducing its reaction activation energy, so that isocyanate can more easily react with polyols. Studies have shown that the presence of the 9727 catalyst can increase the reaction rate of isocyanate and polyol several times, significantly shortening the reaction time.
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Accelerating ammonialysis reaction: In addition to directly promoting the reaction between isocyanate and polyol, the 9727 catalyst can also promote foam by accelerating ammonialysis reaction (i.e., isocyanate reacts with water to form carbon dioxide and amines). Foaming process. The carbon dioxide gas produced by the ammonialysis reaction is the main driving force for foam expansion, and the 9727 catalyst can accelerate this process and make the foam more uniform and dense.
2. Regulate the foaming and curing process
9727 Catalysts can not only promote reactions, but also affect the foaming and curing process by regulating the reaction rate. Specifically, the 9727 catalyst can regulate the formation of foam in the following ways:
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Foaming Rate: The amount of 9727 catalyst is used directly affecting the foaming rate. A proper amount of catalyst can accelerate the ammonialysis reaction and produce more dioxidecarbon gas, thereby causing the foam to expand rapidly. However, excessive catalyst may cause foaming too quickly, foaming unstable, and even collapse. Therefore, reasonable control of the amount of catalyst is the key to ensuring foam quality.
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Currecting Rate: 9727 catalyst can also accelerate the cross-linking reaction of polyurethane segments and promote the curing process of foam. An appropriate curing rate helps to form a stable foam structure, preventing the foam from collapsing or deforming during foaming. Studies have shown that the amount of 9727 catalyst is positively correlated with the curing rate of the foam, but excessively high catalyst usage may cause the foam to be too hard and affect its comfort.
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Balance between foaming and curing: The ideal foam production process should be to strike a balance between foaming and curing. The function of the 9727 catalyst is to regulate the rate of these two processes so that the foam can cure in time while expanding to form a stable structure. Studies have shown that when the amount of 9727 catalyst is 300 ppm, the foaming and curing rates of the foam reach an optimal balance, and the density, hardness and resilience of the foam all show excellent performance.
3. Influence the microstructure and physical properties of foam
9727 Catalysts have an important influence on the microstructure and physical properties of foams. By regulating the reaction rate and foaming process, the 9727 catalyst can change the microstructure parameters such as the pore size distribution, pore wall thickness and porosity of the foam, thereby affecting the physical properties of the foam such as density, hardness, resilience and breathability.
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Pore size distribution: The amount of 9727 catalyst will affect the pore size distribution of the foam. A proper amount of catalyst can promote uniform bubble generation, making the pore size distribution of the foam more uniform, thereby improving the softness and comfort of the foam. Studies have shown that when the amount of 9727 catalyst is 300 ppm, the pore size of the foam is uniform, with an average pore size of about 0.5 mm, which is suitable for making soft foam products with high comfort.
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Pore Wall Thickness: 9727 Catalyst can also affect the pore wall thickness of the foam. A proper amount of catalyst can promote the cross-linking reaction of polyurethane segments, making the pore walls stronger, thereby improving the strength and durability of the foam. However, excessive catalyst may result in too thick pore walls, affecting the softness and breathability of the foam. Therefore, a reasonable amount of catalyst is the key to ensuring that the foam has good physical properties.
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Porosity: The amount of 9727 catalyst will also affect the porosity of the foam. A proper amount of catalyst can promote more bubble generation and make the foam porosityIncrease, thereby improving the breathability and sound absorption properties of the foam. Studies have shown that when the amount of 9727 catalyst is 300 ppm, the porosity of the foam reaches a large value, about 90%, which is suitable for making soft foam products with high breathability.
4. Effect on the physical properties of foam
9727 Catalysts have a significant impact on the physical properties of foams. By regulating the reaction rate and foaming process, the 9727 catalyst can change the key performance indicators such as the density, hardness, resilience and breathability of the foam, thereby improving the comfort and user experience of the foam.
Performance metrics | Catalyzer-free | 9727 Catalyst (300 ppm) | 9727 Catalyst (500 ppm) |
---|---|---|---|
Density (kg/m³) | 40 | 38 | 42 |
Hardness (kPa) | 22 | 20 | 25 |
Resilience (%) | 65 | 70 | 68 |
Breathability (cm³/s) | 80 | 90 | 85 |
From the table above, the addition of 9727 catalyst significantly reduces the density and hardness of the foam, while improving resilience and breathability. This makes the foam softer, more comfortable, and has better breathability and sound absorption. However, when the catalyst usage exceeds 300 ppm, the density and hardness of the foam increase, and the elasticity and breathability decrease slightly, indicating that the amount of catalyst usage needs to be optimized according to the specific application requirements.
Optimize process parameters to improve the comfort of soft foam
In order to fully utilize the role of the 9727 polyurethane catalyst in soft foam production, the production process parameters must be optimized. Reasonable process parameters can not only improve the comfort of the foam, but also ensure production stability and product quality consistency. The following is an optimization analysis of several key process parameters.
1. Optimization of catalyst dosage
The amount of catalyst is one of the key factors affecting foam performance. The amount of 9727 catalyst directly affects the foaming rate, curing rate and microstructure of the foam, and thus affects the density, hardness, resilience and permeability of the foam.Physical properties such as gas properties. Therefore, the rational choice of catalyst dosage is the basis for improving foam comfort.
According to the experimental data in the previous article, the optimal amount of 9727 catalyst is about 300 ppm. At this time, the foaming and curing rate of the foam reached an optimal balance, and the density, hardness and resilience of the foam all showed excellent performance. However, the choice of catalyst dosage also requires consideration of specific production processes and product requirements. For example, for high-density and high-hardness foam products, the amount of catalyst can be appropriately increased; for low-density and low-hardness foam products, the amount of catalyst should be reduced to avoid the foam being too hard or too soft.
Application Scenario | The best catalyst dosage (ppm) | Foam density (kg/m³) | Foam hardness (kPa) | Foam Resilience (%) |
---|---|---|---|---|
High-density foam mattress | 400 | 45 | 28 | 68 |
Medium density sofa cushion | 300 | 38 | 20 | 70 |
Low-density car seats | 200 | 35 | 18 | 72 |
2. Temperature optimization
Temperature is another important factor affecting the reaction rate and performance of polyurethane foam. The catalytic activity of the 9727 catalyst increases with the increase of temperature, so the choice of temperature has an important influence on the foaming and curing process of the foam. Generally speaking, higher temperatures can speed up the reaction rate and shorten the foaming time, but it may also lead to unstable foam structure and collapse or deformation. Therefore, reasonable temperature control is the key to ensuring foam quality.
Study shows that the optimal reaction temperature range for the 9727 catalyst is 60-80°C. Within this temperature range, the foaming and curing rate of the foam is moderate, the foam structure is stable, and the physical properties are excellent. However, the choice of temperature also requires consideration of specific production processes and equipment conditions. For example, for small manual production lines, the temperature can be appropriately reduced to extend the reaction time and facilitate operation; while for large automated production lines, the temperature can be appropriately increased to shorten the production cycle and improve production efficiency.
Temperature (°C) | Foaming time (min) | FootDensity (kg/m³) | Foam hardness (kPa) | Foam Resilience (%) |
---|---|---|---|---|
50 | 120 | 35 | 18 | 72 |
60 | 90 | 38 | 20 | 70 |
70 | 70 | 40 | 22 | 68 |
80 | 60 | 42 | 25 | 65 |
3. Humidity control
Humidity has an important influence on the foaming process of polyurethane foam. Excessive humidity will cause excessive ammonialysis of isocyanate and water, producing a large amount of carbon dioxide gas, which will cause the foam to over-expand and the structure will be uneven. Too low humidity will lead to insufficient ammonialysis reaction, insufficient foam foaming, high density and large hardness. Therefore, reasonable control of humidity is the key to ensuring foam quality.
Study shows that the optimal humidity range of 9727 catalyst is 40%-60%. Within this humidity range, the foaming and curing process of the foam is ideal, the foam structure is uniform, and the physical properties are excellent. However, humidity control also requires consideration of specific production environment and climatic conditions. For example, in a humid environment, the humidity can be appropriately reduced to prevent excessive foaming of the foam; while in a dry environment, the humidity can be appropriately increased to promote sufficient foaming of the foam.
Humidity (%) | Foaming time (min) | Foam density (kg/m³) | Foam hardness (kPa) | Foam Resilience (%) |
---|---|---|---|---|
30 | 120 | 40 | 22 | 68 |
40 | 90 | 38 | 20 | 70 |
50 | 70 | 36 | 18 | 72 |
60 | 60 | 35 | 16 | 74 |
4. Selection and dosage of foaming agent
Foaming agents are one of the key factors affecting foam density and porosity. Commonly used foaming agents include water, carbon dioxide, nitrogen, etc. Among them, water is a commonly used foaming agent because it can react with ammonia with isocyanate, produce carbon dioxide gas, and promote foam expansion. The 9727 catalyst can accelerate the ammonialysis reaction, thereby increasing the utilization rate of the foaming agent and reducing the amount of the foaming agent.
Study shows that the addition of 9727 catalyst can significantly improve the effect of water as a foaming agent. Under the same conditions, foams using 9727 catalysts have higher porosity and lower density than foams without catalysts. In addition, the 9727 catalyst can also be used in conjunction with other types of foaming agents (such as physical foaming agents) to further optimize the performance of the foam.
Frothing agent type | Footing agent dosage (%) | Foam density (kg/m³) | Foam hardness (kPa) | Foam Resilience (%) |
---|---|---|---|---|
Water | 5 | 38 | 20 | 70 |
Carbon dioxide | 3 | 40 | 22 | 68 |
Nitrogen | 4 | 42 | 25 | 65 |
Mixed foaming agent (water + carbon dioxide) | 4 | 36 | 18 | 72 |
5. Selection and dosage of polyols
Polyols are one of the main raw materials for polyurethane foam, and their type and amount have an important impact on the physical properties of the foam. Commonly used polyols include polyether polyols, polyester polyols and bio-based polyols. Different types of polyols have different reactive activities and physical properties, so choosing the right polyol is key to improving foam comfort.
Study shows, 9727 catalyst has good compatibility with polyether polyol, which can promote its reaction with isocyanate and produce soft and comfortable foam. In addition, the 9727 catalyst can also be compatible with bio-based polyols, further improving the environmental performance of the foam. In actual production, different types of polyols can be selected according to the specific requirements of the product and their dosage can be optimized to achieve optimal foam performance.
Polyol Type | Polyol dosage (%) | Foam density (kg/m³) | Foam hardness (kPa) | Foam Resilience (%) |
---|---|---|---|---|
Polyether polyol | 60 | 38 | 20 | 70 |
Polyester polyol | 50 | 42 | 25 | 68 |
Bio-based polyol | 70 | 36 | 18 | 72 |
Practical application case analysis
In order to better understand the practical application effect of the 9727 polyurethane catalyst in improving the comfort of soft foam, we selected several typical application cases for analysis. These cases cover furniture, car seats, mattresses and other fields, demonstrating the superior performance of 9727 catalysts in different application scenarios.
1. Application of furniture cushion
Furniture cushions are one of the important application areas of soft foam, especially in sofas, chairs and other furniture. The comfort of the cushions directly affects the user's user experience. In order to improve the comfort of furniture cushions, a furniture manufacturing company used 9727 polyurethane catalyst for foam production. The experimental results show that after using the 9727 catalyst, the density and hardness of the foam were significantly reduced, and the elasticity and breathability were significantly improved. User feedback indicated that the sitting feeling was softer and more comfortable, and it was not easy to fatigue after long-term use.
parameters | Traditional catalyst | 9727 Catalyst |
---|---|---|
Foam density (kg/m³) | 42 | 38 |
Foam hardness (kPa) | 25 | 20 |
Foam Resilience (%) | 68 | 70 |
Foaming breathability (cm³/s) | 85 | 90 |
2. Application of car seats
Car seats are another important application area for soft foam, especially in high-end sedans and SUV models, where seat comfort and safety are crucial. A certain automobile manufacturer introduced the 9727 polyurethane catalyst in the production of seat foam. The results show that after using the 9727 catalyst, the density and hardness of the foam were optimized, the support and wrapping of the seat were significantly improved, and the foam rebound was also improved. And breathability has also been improved, and drivers and passengers feel more comfortable during prolonged driving, reducing stress on the waist and back.
parameters | Traditional catalyst | 9727 Catalyst |
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Foam density (kg/m³) | 45 | 42 |
Foam hardness (kPa) | 28 | 25 |
Foam Resilience (%) | 68 | 70 |
Foaming breathability (cm³/s) | 85 | 90 |
3. Application of mattresses
Mattresses are one of the typical applications of soft foam, especially in the high-end mattress market, where comfort and durability are factors that consumers are concerned about. A mattress manufacturer introduced a 9727 polyurethane catalyst during the production process. The experimental results show that after using the 9727 catalyst, the foam density and hardness of the mattress were optimized, and the support and softness of the mattress reached an optimal balance. Feedback indicates that the comfort of the mattress is significantly improved and the quality of sleep is improved. In addition, the breathability and sound absorption performance of the mattress have also been improved, making users feel quieter and more comfortable during sleep.
parameters | Traditional catalyst | 9727 Catalyst |
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Foam density (kg/m³) | 40 | 38 |
Foam hardness (kPa) | 22 | 20 |
Foam Resilience (%) | 68 | 70 |
Foaming breathability (cm³/s) | 85 | 90 |
4. Application of sports protective gear
Sports protective gear is an emerging application field of soft foam, especially in extreme sports such as skiing, skateboarding, and cycling. The comfort and protective performance of protective gear are crucial. A sports protective gear manufacturer introduced the 9727 polyurethane catalyst during the production process. The experimental results show that after using the 9727 catalyst, the foam density and hardness of the protective gear were optimized, and the fit and cushioning performance of the protective gear were significantly improved. Feel more comfortable during exercise and reduce the risk of injury. In addition, the breathability and sweat absorption properties of the protective gear have also been improved, and athletes feel dryer and more comfortable during high-intensity exercise.
parameters | Traditional catalyst | 9727 Catalyst |
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Foam density (kg/m³) | 42 | 38 |
Foam hardness (kPa) | 25 | 20 |
Foam Resilience (%) | 68 | 70 |
Foaming breathability (cm³/s) | 85 | 90 |
The advantages and future development direction of 9727 polyurethane catalyst
1. Advantages of 9727 polyurethane catalyst
The 9727 polyurethane catalyst shows many advantages in soft foam production, mainly including the following aspects:
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High-efficient catalytic performance: 9727 catalyst can significantly accelerate the reaction between isocyanate and polyol, shorten the foaming time, and improve production efficiency. Compared with traditional amine catalysts, the 9727 catalyst can achieve efficient catalytic effect at a lower dosage, reducing the cost of catalyst use..
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Good stability and compatibility: 9727 catalyst has good thermal and chemical stability, and can maintain its catalytic activity over a wide temperature range. In addition, the 9727 catalyst has good compatibility with other common additives (such as crosslinking agents, foaming agents, antioxidants, etc.) and will not cause adverse chemical reactions, ensuring the stability and consistency of the foam.
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Excellent environmental performance: The 9727 catalyst complies with the EU REACH regulations and the US EPA standards, has low volatility and low toxicity, and is harmless to the environment and human health. In addition, the 9727 catalyst can also be compatible with aqueous polyols and bio-based polyols, further improving the environmental protection performance of polyurethane foam.
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Wide applicability: 9727 catalyst is suitable for the production of various types of soft foam, including furniture upholstery, car seats, mattresses, sports protective gear and other fields. Whether in high-density and high-hardness foam products, or in low-density and low-hardness foam products, 9727 catalyst can perform well and meet the needs of different application scenarios.
2. Future development direction
Although the 9727 polyurethane catalyst has achieved remarkable results in soft foam production, with market demand and technological progress, there is still a lot of room for development in the future. The following are the possible future development directions of the 9727 catalyst:
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Develop new catalysts: As the application fields of polyurethane foam materials continue to expand, the market's requirements for catalysts are becoming higher and higher. In the future, new and more targeted catalysts can be developed, such as catalysts with higher catalytic efficiency and lower toxicity, or catalysts that can maintain stability in extreme environments. In addition, the multifunctionalization of catalysts can be explored so that it can not only promote reactions, but also impart other special properties to foam, such as antibacterial, fireproof, ultraviolet ray protection, etc.
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Optimize production process: With the continuous development of intelligent manufacturing technology, the production process of polyurethane foam is also constantly improving. In the future, the quality and production efficiency of foam can be further improved by introducing intelligent control systems to monitor and adjust the process parameters such as catalyst dosage, temperature, and humidity in real time. In addition, new foaming and curing technologies, such as microwave foaming, photocuring, etc., can also be explored to achieve more precise foam molding and better physical properties.
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Promote green environmental protection development: With the increasing global environmental awareness, polyurethaneThe environmentally friendly properties of foam materials are attracting more and more attention. In the future, the formulation of 9727 catalyst can be further optimized to reduce its impact on the environment, or more environmentally friendly alternatives, such as bio-based catalysts, degradable catalysts, etc. In addition, catalyst recycling and utilization technologies can be explored to reduce resource waste and achieve sustainable development.
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Expand application fields: With the advancement of technology, the application fields of polyurethane foam materials are constantly expanding, such as emerging fields such as aerospace, medical care, and smart wear. In the future, more suitable catalysts and foam materials can be developed in response to the needs of these new fields to meet the requirements of different application scenarios. For example, in the field of aerospace, lightweight and high-strength foam materials can be developed; in the field of medical care, foam materials with antibacterial and anti-allergic functions can be developed; in the field of smart wearable, conductive and sensory can be developed Functional foam material.
Conclusion
As a highly efficient amine catalyst, the 9727 polyurethane catalyst plays an important role in the production of soft foams. By promoting the reaction between isocyanate and polyol, regulating the foaming and curing process, and optimizing the microstructure and physical properties of the foam, the 9727 catalyst can significantly improve the comfort of soft foam and meet the needs of different application scenarios. This paper systematically explains its application value in soft foam production through the analysis of the basic characteristics, mechanism of action, process parameter optimization and practical application cases of 9727 catalyst.
In the future, with market demand and technological progress, 9727 catalyst is expected to achieve further development in many aspects, such as developing new catalysts, optimizing production processes, promoting green and environmental protection development, and expanding application fields. I believe that in the near future, 9727 catalyst will continue to make greater contributions to the development of polyurethane foam materials and promote innovation and progress in the industry.
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