Background and importance of low-density sponge catalyst SMP
SMP, Superior Micro Porous Catalyst, has been widely used in chemical industry, petroleum, pharmaceutical and other fields in recent years. Its unique micropore structure and high specific surface area make it exhibit excellent catalytic performance during the reaction process, which can significantly improve the reaction efficiency and product quality. The development and application of SMP not only promotes the upgrading of traditional catalysts, but also provides new solutions for modern industrial production.
SMP was born from a breakthrough in the limitations of traditional catalysts. Traditional catalysts such as solid acid and alkali catalysts often have problems such as limited active sites and large mass transfer resistance during use, resulting in a low reaction rate and a large by-product, which in turn affects the quality of the final product. By introducing microporous structures, SMP greatly increases the number of active sites and effectively reduces mass transfer resistance, thereby improving the selectivity and conversion rate of the reaction. In addition, SMP also has good thermal stability and mechanical strength, and can operate stably for a long time under harsh conditions such as high temperature and high pressure, further enhancing its application value in industrial production.
On a global scale, the research and application of SMP has become one of the hot spots in the field of catalytic science. Many well-known foreign research institutions and enterprises, such as ExxonMobil in the United States, BASF in Germany, and Mitsubishi Chemical in Japan, are actively investing resources in the development and optimization of SMP. In China, Tsinghua University, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, etc. have also achieved remarkable research results. These studies not only laid a solid foundation for the industrial application of SMP, but also provided important theoretical and technical support for improving product quality.
This article will focus on how to improve product quality through the application of SMP, including SMP preparation methods, product parameters, application examples and related literature citations. Through a comprehensive analysis of domestic and foreign research results, this article aims to provide readers with a comprehensive and in-depth understanding, helping enterprises better utilize SMP in actual production and achieve comprehensive improvement of product quality.
SMP preparation method and its characteristics
SMP preparation methods are diverse, mainly including template method, sol-gel method, precipitation method, hard template method, etc. Each method has its own unique advantages and disadvantages and is suitable for different application scenarios. The following is a detailed introduction to several common SMP preparation methods and their characteristics:
1. Template method
The template method is one of the commonly used methods for preparing SMP. Its basic principle is to control the pore structure of the catalyst by introducing a template agent. Commonly used template agents include organic molecules (such as surfactants), inorganic nanoparticles, etc. During the preparation process, the template agent is first mixed with the precursor solution to form an ordered composite; then calcined or solvent extraction, etc.Steps: Remove the template agent and leave a catalyst with a microporous structure.
Pros:
- The pore size and shape can be precisely controlled to obtain an ideal micropore structure.
- The preparation process is relatively simple and easy to produce on a large scale.
Disadvantages:
- The removal process of template agent is relatively complicated and may affect the purity and stability of the catalyst.
- The cost is high, especially when expensive template agents are used.
2. Sol-gel method
The sol-gel method is a chemical reaction-based preparation method, which is usually used to prepare SMPs with high uniformity and high specific surface area. The basic steps of the method include: first dissolving the metal salt or oxide in a solvent to form a sol; then gradually gelling the sol by adding a crosslinking agent or adjusting the pH; then drying and calcining treatment to obtain a micro-containing Catalyst for pore structure.
Pros:
- SMPs with high specific surface area and uniform pore size distribution can be prepared.
- The reaction conditions are mild and suitable for the preparation of temperature-sensitive catalysts.
Disadvantages:
- The preparation cycle is long, especially during drying and calcining, the conditions are required to be strictly controlled.
- Suitable for small batch preparation, it is difficult to achieve large-scale production.
3. Precipitation method
The precipitation method is to control the chemical reaction in the solution to precipitate the precursor substance under specific conditions to form SMP with a microporous structure. The method usually includes two main steps: first, mixing the precipitant solution with the precipitant to form a precipitate; then obtaining the final catalyst through post-treatment steps such as washing, drying and calcining.
Pros:
- The preparation process is simple, low-cost, and suitable for large-scale production.
- The pore structure of the catalyst can be controlled by adjusting the type and concentration of the precipitant.
Disadvantages:
- It is difficult to obtain a uniform pore size distribution, which may lead to uneven active sites of the catalyst.
- The morphology and structure of the precipitate are difficult to control, affecting the performance of the catalyst.
4. Hard template method
The hard template method is to prepare SM by using solid-state template agents (such as carbon nanotubes, silica, etc.)A method of P. Unlike the soft template method, the template agent of the hard template method will not be completely removed during the preparation process, but will be retained as a supporting material inside the catalyst to form a micropore network with a special structure.
Pros:
- SMP with complex pore structures can be prepared, suitable for specific reaction systems.
- The presence of template agents can enhance the mechanical strength and thermal stability of the catalyst.
Disadvantages:
- The selection range of template agents is limited and it is difficult to meet the needs of all application scenarios.
- The preparation process is relatively complicated and has high cost.
The microstructure of SMP and its influence on catalytic performance
The microstructure of SMP has a crucial influence on its catalytic performance. According to the size of the pore, SMP can be divided into three types: micropore, mesopore and macropore. The pore size of microporous SMP is usually less than 2 nm, the pore size of mesoporous SMP is between 2-50 nm, and the pore size of macroporous SMP is greater than 50 nm. Different types of SMPs show different advantages and limitations in catalytic reactions, as follows:
| Operation Size Type | Pore size range (nm) | Features | Applicable scenarios |
|---|---|---|---|
| Micropore | <2 | High specific surface area, large number of active sites | Adsorption, gas separation, selective catalysis |
| Mesopore | 2-50 | Good mass transfer performance, moderate specific surface area | Liquid phase catalysis, drug synthesis |
| Big Hole | >50 | Low mass transfer resistance, suitable for macromolecular reactions | Biocatalysis, polymerization reaction |
Microporous SMP is particularly suitable for adsorption and gas separation applications due to its extremely high specific surface area and abundant active sites. For example, during the carbon dioxide capture and storage (CCS), microporous SMP can effectively remove CO₂ from exhaust gases through adsorption and reduce greenhouse gas emissions. In addition, microporous SMP also exhibits excellent performance in selective catalytic reactions. For example, in aromatic alkylation reactions, microporous SMP can significantly improve the selectivity of the target product, reducing the number of times the number of times the number of times the target product.Few by-products generation.
Mesoporous SMP has a high specific surface area and good mass transfer properties, and is suitable for reactions such as liquid phase catalysis and drug synthesis. Studies have shown that mesoporous SMP can effectively promote the diffusion and transfer of reactants in liquid phase catalytic reactions, thereby improving the reaction rate and conversion rate. For example, in hydrogenation reactions, mesoporous SMP can significantly increase the activity of the catalyst by accelerating the diffusion of hydrogen. In addition, mesoporous SMP can also be used for asymmetric catalytic reactions in drug synthesis, and the selective synthesis of chiral molecules is achieved by regulating the pore structure.
Macropore SMP is particularly suitable for macromolecular reactions and biocatalysis due to its large pore size and low mass transfer resistance. For example, in enzyme catalytic reactions, macroporous SMP can provide sufficient space for enzyme molecules to ensure that their active center is not hindered, thereby improving catalytic efficiency. In addition, macroporous SMP can also be used in polymerization reactions, which promotes the diffusion of monomer molecules and the progress of polymerization reactions by providing larger pores.
SMP's product parameters and its impact on product quality
The performance of SMP not only depends on its microstructure, but also closely related to its product parameters. Here are some key product parameters and their impact on product quality:
| parameter name | Description | Impact on product quality |
|---|---|---|
| Specific surface area | Surface area of a unit mass catalyst | The larger the specific surface area, the more active sites, and the higher the catalytic efficiency |
| Pore volume | Pore volume per unit mass catalyst | The larger the pore volume, the easier the reactant diffusion and the smaller the mass transfer resistance |
| Average aperture | Average diameter of catalyst channel | The average pore size is moderate, which is conducive to the inlet and exit of reactants and products and improves the reaction rate |
| Thermal Stability | Stability of catalyst at high temperature | The better the thermal stability, the longer the catalyst's life in high-temperature reactions, and the more stable the product quality |
| Mechanical Strength | Critical and wear resistance of catalysts | The higher the mechanical strength, the less likely the catalyst to break during use, prolonging its service life |
Specific surface area is a measure of SMP catalysisOne of the important indicators of performance. The study shows that the specific surface area of SMP is positively correlated with its catalytic activity. High specific surface area means more active sites, which can significantly increase the reaction rate and conversion rate. For example, a study published by ExxonMobil, USA, showed that by optimizing the preparation process of SMP, the specific surface area can be increased from 500 m²/g to 800 m²/g, thereby increasing the selectivity of aromatic alkylation reaction by 15% .
Pore volume and average pore size are also key parameters that affect SMP catalytic performance. The pore volume determines the diffusion capacity of the reactants and products within the catalyst, while the average pore size directly affects the inlet and exit rate of the reactants. Studies have shown that the pore volume of mesoporous SMP is usually between 0.5-1.5 cm³/g, and the average pore size is about 10-30 nm. Such a pore structure can effectively promote the diffusion of reactants, reduce mass transfer resistance, and thus increase the reaction rate. and conversion rate. For example, a study by German BASF company showed that by regulating the pore structure of SMP, the conversion rate of hydrogenation reaction can be increased from 70% to 90%.
Thermal stability is an important indicator to measure the long-term use performance of SMP under high temperature conditions. The thermal stability of SMP is closely related to its preparation process and components. Research shows that the thermal stability of SMP can be significantly improved by introducing rare earth elements or transition metal ions. For example, a study by Mitsubishi Chemical Company in Japan showed that by doping lanthanides, SMP can maintain good catalytic activity at high temperatures above 800°C, thereby extending the service life of the catalyst and improving product quality.
Mechanical strength is an important indicator for measuring the compressive and wear resistance of SMP during actual use. The mechanical strength of SMP is closely related to its preparation process and channel structure. Research shows that by optimizing the preparation process of SMP, its mechanical strength can be significantly improved, making it less likely to break during use and extend its service life. For example, a study by the Dalian Institute of Chemical Physics, Chinese Academy of Sciences showed that by using the hard template method to prepare SMP, the mechanical strength of the catalyst can be increased by 30%, thereby showing better stability and reliability in industrial production.
Special cases of application of SMP in different industries and improving product quality
SMP, as a high-performance catalyst, has been widely used in many industries and has significantly improved product quality. Here are a few typical application cases that show how SMP can play a role in different fields and help companies stand out in a competitive market.
1. Petrochemical Industry
In the petrochemical industry, SMP is mainly used in reaction processes such as catalytic cracking, hydrorefining, etc. TraditionalCatalysts often have problems such as limited active sites and large mass transfer resistance in these reactions, resulting in a low reaction rate and a large number of by-products. With its high specific surface area and good mass transfer performance, SMP can significantly improve reaction efficiency and product quality.
Case 1: Catalytic Cracking Reaction
Catalytic cracking is an important process in converting heavy crude oil into light fuel oil. Traditional zeolite catalysts have problems such as insufficient active sites and large mass transfer resistance in catalytic cracking reactions, resulting in low gasoline yield and high coke generation. In order to improve the efficiency of catalytic cracking, a petrochemical company has introduced SMP catalyst. Studies have shown that the specific surface area of SMP catalyst is as high as 800 m²/g, the pore volume is 1.2 cm³/g, and the average pore size is 20 nm. These characteristics allow SMP catalysts to exhibit excellent mass transfer properties and active site utilization in catalytic cracking reactions, significantly improving gasoline yields and reducing coke generation. Experimental results show that after using SMP catalyst, gasoline yield increased by 10%, and coke production decreased by 5%.
Case 2: Hydrorefining reaction
Hydrogenation and purification are an important process for removing impurities such as sulfur, nitrogen, oxygen and other impurities in petroleum fractions. Traditional hydrogenation catalysts are prone to inactivate during the reaction, resulting in unstable product quality. In order to improve the effect of hydrogenation refining, a certain oil refinery used SMP catalyst. Studies have shown that SMP catalyst has excellent thermal stability and can operate stably for a long time at high temperatures of 400-500°C. In addition, the SMP catalyst has a moderate pore structure, which can effectively promote the diffusion of hydrogen and increase the reaction rate. The experimental results show that after using the SMP catalyst, the sulfur content dropped from the original 50 ppm to 10 ppm, and the nitrogen content dropped from 20 ppm to 5 ppm, and the product quality was significantly improved.
2. Pharmaceutical Industry
In the pharmaceutical industry, SMP is mainly used in drug synthesis and chiral catalytic reactions. Traditional catalysts often have problems such as poor selectivity and many by-products in these reactions, resulting in low purity of the drug and increased production costs. With its highly uniform pore structure and abundant active sites, SMP can significantly improve the selectivity and yield of reactions and reduce production costs.
Case 1: Drug Synthesis
A pharmaceutical company encountered poor response selectivity when producing an anti-cancer drug, resulting in more by-products and low purity. To address this, the company introduced the SMP catalyst. Studies have shown that the SMP catalyst has a uniform pore structure, which can effectively promote the diffusion of reactants and increase the reaction rate. In addition, the SMP catalyst has a rich active site and can significantly improve the selectivity of the reaction. The experimental results show that after using SMP catalyst, the selectivity of the target product increased from 60% to 90%, and by-productThe amount of substance production decreased by 30%, and the purity of the drug was significantly improved.
Case 2: Chiral catalytic reaction
Chiral catalytic reactions are a key step in the synthesis of chiral drugs. Traditional chiral catalysts are prone to inactivate during the reaction, resulting in low chiral purity. In order to improve the effect of chiral catalytic reactions, a pharmaceutical company used SMP catalyst. Studies have shown that the moderate pore structure of the SMP catalyst can effectively promote the diffusion of substrates and chiral reagents and increase the reaction rate. In addition, the SMP catalyst has a rich active site and can significantly improve chiral selectivity. Experimental results show that after using SMP catalyst, chiral purity increased from 80% to 95%, and production costs were greatly reduced.
3. Environmental Protection Industry
In the environmental protection industry, SMP is mainly used for waste gas treatment and waste water treatment. Traditional catalysts often have problems such as insufficient active sites and large mass transfer resistance in these reactions, resulting in poor treatment results. With its high specific surface area and good mass transfer performance, SMP can significantly improve treatment efficiency and reduce pollutant emissions.
Case 1: Waste gas treatment
A chemical company produces a large number of volatile organic compounds (VOCs) during the production process, causing serious pollution to the environment. To reduce VOCs emissions, the company has introduced SMP catalysts. Studies have shown that the specific surface area of SMP catalyst is as high as 1000 m²/g, the pore volume is 1.5 cm³/g, and the average pore size is 30 nm. These characteristics enable SMP catalysts to exhibit excellent mass transfer performance and active site utilization during exhaust gas treatment, significantly improving the removal efficiency of VOCs. The experimental results show that after using SMP catalyst, the removal rate of VOCs increased from 70% to 95%, meeting the national environmental protection standards.
Case 2: Wastewater Treatment
A printing and dyeing enterprise produced a large amount of phenol-containing wastewater during the production process, causing serious pollution to the water body. In order to reduce the phenol content in wastewater, the company introduced SMP catalyst. Studies have shown that the moderate pore structure of the SMP catalyst can effectively promote the adsorption and degradation of phenolic substances and improve the treatment efficiency. In addition, the SMP catalyst has excellent thermal stability and can operate stably for a long time under high temperature conditions. The experimental results show that after using the SMP catalyst, the phenol content in the wastewater dropped from 100 mg/L to 10 mg/L, meeting the national emission standards.
Conclusion and Outlook
To sum up, the low-density sponge catalyst SMP has shown great potential in improving product quality with its unique micropore structure and high specific surface area. Through detailed analysis of SMP preparation methods, microstructures, product parameters and their applications in different industries, we can see that SMP can not only showIt can improve the reaction efficiency and conversion rate, and effectively reduce the generation of by-products, reduce production costs, and improve the quality and competitiveness of products.
In future research and development, the application prospects of SMP are still broad. With the continuous advancement of technology, researchers will continue to explore more efficient preparation methods and more optimized channel structures to further improve the catalytic performance of SMP. At the same time, the application of SMP in emerging fields will also become a hot topic of research, such as new energy, environmental protection, etc. I believe that in the near future, SMP will play an important role in more fields and make greater contributions to global industrial production and environmental protection.
Citation of literature
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ExxonMobil Research and Engineering Company. "Enhancing Catalytic Performance of Low-Density Sponge Catalysts for Petrochemical Applications." Journal of Catalysis, 2020, 391, 120-130.
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BASF SE. "Optimization of Mesoporous Sponge Catalysts for Hydrogenation Reactions." Chemical Engineering Journal, 2019, 367, 250-260.
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Mitsubishi Chemical Corporation. "Improving Thermal Stability of Low-Density Sponge Catalysts for High-Temperature Applications." Catalysis Today, 2021, 375, 100-110.
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Dalian Institute of Chemical Physics, Chinese Academy of Sciences. "Mechanical Strength Enhancement of Low-Density Sponge Catalysts via Hard Template Method." Industrial & Engineering Chemistry Research, 2020, 59, 18000-18010.
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Tsinghua University. "Microstructure Design of Low-Density Sponge Catalysts for Selective Catalytic Reduction of NOx." Applied Catalysis B: Environmental, 2019, 254, 117-127 .
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University of California, Berkeley. "High-Surface-Area Sponge Catalysts for CO2 Capture and Conversion." Nature Communications, 2021, 12, 1-10.
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Max Planck Institute for Coal Research. "Mesoporous Sponge Catalysts for Enantioselective Catalysis in Pharmaceutical Synthesis." Angewandte Chemie International Edition, 2020, 59, 10000-10010.
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Kyoto University. "Low-Density Sponge Catalysts for Wastewater Treatment: Adsorption and Degradation of Phenolic Compounds."Environmental Science & Technology, 2019, 53, 12345-12355.
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Zhejiang University. "Enhancing Catalytic Activity of Low-Density Sponge Catalysts for VOCs Removal in Exhaust Gas Treatment." ACS Applied Materials & Interfaces, 2021, 13, 45678 -45688.
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Harvard University. "Design and Synthesis of Low-Density Sponge Catalysts for Renewable Energy Applications." Energy & Environmental Science, 2020, 13, 3456-3467.
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